Intumescent coatings are known as ‘reactive paints’, because when the paint is exposed to heat, it reacts.
When an intumescent paint is subjected to temperatures in excess of 120oC, it turns back to a liquid state, when it then increases in volume while decreasing in density, thus creating a heat resistant barrier. The subsequent charring delays the detrimental effect extreme heat has on structural steel, offering valuable time for occupants to vacate the building and emergency services to tend the fire.
The paint itself can expand to up to 50 times its thickness and forms a carbon layer. In the case of intumescent coatings for steel, the carbon layer acts to insulate the steel and maintain a temperature below 550oC or 620oC for a given period of time such as 30, 60, 90 or 120 minutes.
During a fire, it is imperative that the structural elements of a building are protected so that they don’t reach the critical failure temperature. For structural steelwork this is between 550oC and 620oC. Below this temperature, the steel maintains a state of elasticity, meaning that it can bend or deflect then return to its original state once the force has been removed. If the temperature goes above the critical temperature, structural steel under load will take on a state known as ‘plastic’ and lose its load bearing capacity and potentially collapse.
Concrete critical state is dependent on the critical temperature of the reinforcing bars (usually 350oC to 500oC) and the temperature reaching 500oC inside the concrete element. The critical temperature of wood correlates to the residual section of the timber load bearing element after a fire.